Strength of Glass
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Glass failure always results from a tensile component of stress. The breaking stresses of glass are far from uniform. They depend on the method of manufacturer and on the subsequent history, even if a glass with a fire-polished surface is very strong.
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Abraded Strength
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Breaking stress of glass measured after a processing of controlled abrasion. This is used to determine the strength for practical use.
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Static Fatigue
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The decrease in the breaking stress of glass with increased duration of load under conditions of static loading.
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Dynamic Fatigue
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Decrease of the breaking stress of glass with increased duration of load under cyclic loading conditions.
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Stress Relaxation
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The phenomena in which the stress in glass decreases with time due to the thermal effect.
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Machinability
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The ease with which a material can be machined by the process such as cutting or shaping.
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Liquidus Temperature
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The maximum temperature at which equilibrium exists between a molten substance, such as glass, and the primary crystalline phase.
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Crystallization Temperature
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The temperature at which glass is heat-treated for crystallization, or the temperature detected by DTA at which a crystal begins to crystallize.
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Melting Temperature of Crystal
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The temperature detected by DTA at which a crystal begins to melt.
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Phase Separation
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The phenomena in which a melt separates into two liquids with different chemical composition.
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Expansion Coefficient
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The tangent of the linear thermal expansion curve at a specified temperature, or the tangent of the linear thermal expansion between two specified temperatures.
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Melting Temperature
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An arbitrarily defined reference point used for comparison purposes at which the glass viscosity is 100 dPa.s. (ASTM C162) The same temperature with emelting pointf.
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Melting Point
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The range of furnace temperatures within which melting takes place at a commercially desirable rate, and at which the resulting glass generally has a viscosity of 101.5 to 102.5 dPa.s. For purposes of comparing glasses, it is assumed that glass of melting temperature has a viscosity of 102 dPa.s.(ISO 7884-1)
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Working Range
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The range of surface temperature in which glass is formed into ware in a specific process. For comparative purposes, when no specific process is considered, the working range of glass is assumed to correspond to a viscosity range from approximately 103 to 108 dPa.s. (ISO
@7884-1).
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Working Point
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The temperature corresponding to a viscosity of 104 dPa.s. (ISO 7884-1)
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Softening Point
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The temperature at which a glass fiber suspended in a furnace elongates at a specified rate under its own weight during heating. The viscosity at the softening point corresponds to a viscosity of 107.6 dPa.s which depends on the density and the surface tension of the glass.
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Littleton Point
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The same temperature with esoftening pointf.
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Deformation Point
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The temperature at the maximum peak of the thermal expansion curve of glass. This temperature depends on the measurement method of thermal expansion.
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Dilatometric Softening Point
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See edeformation temperaturef.
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Annealing
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A controlled cooling process for glass, designed to reduce the thermal residual stress to a commercially acceptable level, and, in some cases, to modify the structure.
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Annealing Range
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The range of glass temperature in which stress in glass can be released at a commercially practical rate. For purposes of comparing glasses, the annealing range is assumed to correspond with the temperature between the annealing point and the strain point.
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Annealing Point
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At this temperature, the internal stresses of glass are substantially released in a matter of minutes. The viscosity corresponding to this temperature is 1013 to 1013.5 dPa.s and is dependent on the measurement method.
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Glass Transition Temperature
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The temperature, Tg at which glass transforms from an elastic to a viscoelastic material on heating, characterized by the onset of a rapid change in some specific mechanical or thermal property. Observed Tg can vary significantly depending on the property chosen for observation and the experimental technique. Typical methods are dilatometry and DTA.
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Tg (Dilatometric)
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The glass transition temperature determined by means of the thermal expansion curve.
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Tg (DTA)
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The glass transition temperature measured by DTA or DSC(differential scanning calorimetry).
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Transformation Temperature
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The same meaning with 'glass transition temperaturef.
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Strain Point
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At this temperature, the internal stress of glass is substantially released in a matter of hours. The viscosity corresponding to this temperature is 1014.5 to 1015 dPa.s which is depend on measurement method.
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VFT Equation
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Abbreviation for Vogel-Fulcher-Tammann equation. The same equation with 'Fulcher equation'.
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Fulcher Equation
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According to Fulchcr, the viscosity-temperature relationship is conveniently described by the following equation; log (viscosity) = A + B/(T - To) where T is temperature and A, B and To are constants. These constants can be determined using 3 viscosity data. However, the data in the annealing range should not be used.
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Arrhenius Equation
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The temperature dependence of the diffusion coefficient or the electrical conductivity, k, is expressed by the equation, k = Aexp(
|E/RT), where A, E, R and T are a constant, an activation energy, the gas constant and the absolute temperature, respectively.
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Ion Exchange
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The phenomena by which ions in glass are replaced with other ions in surrounding medium (e.g. molten salt) outside of the glass. The major species relating to the exchange are monovalent positive ions such as alkali ions.
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Meltability
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The easiness of melting a glass batch.
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Abbe value
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The reciprocal dispersive power, a value used in optical design, expressed mathematically as: Abbe value = (nd - 1)/(nF - nC), where nd, nF and nC are the refractive indices for the helium line at 587.6 nm, and for the hydrogen line at 486.1 and 656.3 nm, respectively.
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Sellmeier Formula
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The equation that expresses the dependence of the refractive index on the optical wavelength, n2 = 1 + A1L2/(L2 - B1) + A2L2/(L2- B2)+ A3L2/(L2-B3), where n and L are the refractive index and optical wavelength, respectively, and A1, A2, A3, B1, B2 and B3 are constants.
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Dispersion Formula
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The equation that expresses the dependence of the refractive index on the optical wavelength, n2 =A0 + A1L2 + A2L-2 + A3L-4 +A4L-6 + A5L-8, where n and L are the refractive index and optical wavelength respectively, and A0 , A1, A2, A3, A4, and A5 are constants.
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Dispersion
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Variation of refractive index with optical wavelength.
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Total Dispersion
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The same meaning with emean dispersionf.
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Main Dispersion
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The same meaning with emean dispersionf.
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Mean Dispersion F-C
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The refractive index difference from the F line (486.1 nm) to the C line (656.3 nm) of the spectrum, (nF
| nC).
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Relative Partial Dispersion
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The Ratio of the dispersion for optical wavelength x and y to mean dispersion which is expressed as Px,y = (nx-ny)/(nF-nC), where nx, ny nF and nC are the refractive indices for the optical wavelength x, y, c and y.
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Stress Optical Coefficient
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This coefficient is used for the determination of the internal stress of glass converted from the optical path difference measured by a photoelastic technique.
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Transmittance
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The ratio of transmitted light energy to incident light energy, T. In the case of perpendicular incident light to a flat glass surface, T is expressed by the following formula, T=(1-R)2exp(-ax), where R is the reflectivity, a is the absorption coefficient, and x is the thickness of the flat glass, respectively.
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Optical Absorbance
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The light intensity ratio, I/Io, where Io and I are intensity of the incident light and that of the transmitted light through a medium, respectively.
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Optical Density
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D = -log(I/Io)
, where Io and I are the intensity of the incident light and that of the transmitted light through a medium, respectively.
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Internal Transmission
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Transmission of light in a glass body without consideration of surface reflection.
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Reflectance
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The ratio of reflected light to incident light, r. For perpendicular incident light, r=((n-l)/(n+l))2, where n is the refractive index of the glass.
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Optical Absorption Edge
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In a continuous optical spectrum, the optical wavelength at a range longer than that at which optical absorption steeply decreases.
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Optical Gap
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The photon energy, Eg, of Eg=hc/L where L is the wavelength of optical absorption edge, h is Plankfs constant and c is the light velocity.
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Numerical Aperture
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A number, NA, related to the critical angle (a) of a cone of incident light to an optical fiber. When the refractive index of the core and the cladding of the fiber is ni and no , respectively, then NA = sin a =(2ni(ni - no))1/2.
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Electric Conductivity, E and So
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See Arrhenius equation. The electrical conductivity S is expressed by the equation, S = Soexp(
|E/RT).
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DC Volume Resistivity E and ro
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See eArrhenius equationf. The electrical resistivity r is expressed by the equation, r = roexp(E/RT).
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AC Volume Resistivity E and ro
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See eArrhenius equationf. The AC volume resistivity r is expressed by the equation, r = roexp(E/RT).
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Chemical Durability
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The lasting quality (both physical and chemical) of a glass surface. It is frequently evaluated after prolonged contact with water, chemicals or atmosphere in terms of chemical and physical changes in the glass surface, or in terms of changes in the contents of a vessel.
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Additivity Relationship
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Many glass properties (P) obey the following linear relationship. P = p1a1 + p2a2..+ pnan, where pi is the additivity factor for the i'th component, and ai is the content of the i'th component in mass%, mol% mass fraction or mol fraction. Note that a1 + a2..+an = 100 % or 1.
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Dissipation Factor
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The same meaning with eloss tangentf.
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Loss Factor
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The same meaning with 'loss tangent'.
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Tangent Delta
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The same meaning with 'loss tangent'.
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Standard Spectral Lines
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The characteristic narrow optical spectral lines used for the measurement of the optical constants of optical materials. The name, the optical wavelength, the light source and the color of each spectral line is shown in the following table.
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Notation
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t
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s
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r
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C
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C'
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D
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d
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Wavelength /nm
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1013.98
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852,11
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706.52
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656.27
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643.85
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589.24
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587.56
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Light source
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Hg v
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Cs v
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He v
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H
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Cd v
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Na v
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He
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Color
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IR
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IR
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red
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red
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red
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yellow
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yellow
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Notation
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e
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F
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F'
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g
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h
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i
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Wavelength /nm
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546.07
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486.13
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479.99
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435.83
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404.66
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365.01
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Light source
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Hg v
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H
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Cd v
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Hg v
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Hg v
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Hg v
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Color
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Green
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blue
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blue
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blue
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violet
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UV
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Diffusion Coefficient Equation
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See Arrhenius equation. The diffusion coefficient D is expressed by the equation, D = Doexp(
|E/RT).
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(Linear Thermal) Expansion Coefficient
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Tangent of linear thermal expansion curve at certain temperature.
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Transformation Point
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The same meaning with eglass transition temperaturef.
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Weathering
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A phenomena in which the surface of glass deteriorates by the effect of the atmosphere, usually by the humidity.
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